The models describing the flow or the heat and mass transfer in stirred bioreactors can be easily adapted for the continuous phase from the stirred bed bioreactors. But, for the immobilized biocatalyst phase, new models have to be established. Therefore, in this paper the influences of the main factors on mixing for a bioreactor with stirred bed of S. cerevisiae immobilized cells in alginate have been analyzed.. The mixing efficiency continuously increases with rotation speed acceleration for th...
Autori: Anca-Irina Galaction, Anca-Marcela Lupasteanu, Dan Caşcaval
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25116

A series of new Ni(II) poly-phosphinates have been synthesised using Ni(II) acetylacetonate as nickel precursor and a succession of ligands derived from phosphinic acid: ethyl-butyl-phosphinic acid, ethyl-butyl-thio-phosphinic acid, and respectively ethylbutyl-di-thio-phosphinic acid. Chemical analysis gel-chromatography, infrared spectroscopy (IR), spin electronic resonance (RES), X-ray diffraction (XRD), thermal gravimetric analysis (TGA), electrical resistance measurements at different temper...
Autori: Daniel Sutiman, Doina Sibiescu, , Mircea Teodor Nechita
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25118

Contain all the articles from this issueICEEM /02 PLENARY SESSION:"Environmental Engineering and Management in the Context of Sustainable Development"Green technology foresight of high technology: Hype of potentials - The challenges from nanotechnology, Biotechnology and ICTMichael S?¸gaard J?¸rgensenIntrinsic properties of noble metals in catalytic selective reduction of NO by propene in lean burn conditionsAnne Giroir-Fendler, Helleh Saadallah, Adela HaletaICEEM/02 - ENVIRONMENTAL ENGINEERING ...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25178

AbstractThe aim of this work was to obtain Ag - doped zeolite as antibacterial material using natural and sodium form of zeolite from Mirsid Romania with the dimensions ranged between 0.8-1.2 mm. The comparative structural characterization of natural and Ag - doped zeolite were performed using Laser Induced Breakdown Spectroscopy (LIBS), X-ray Diffraction (XRD), Scanning Electron Microscopy (SEM), Atomic Force Microscopy (AFM), and Infrared Spectroscopy (IR). In addition, the ion exchange total ...
Autori: Aurel Iovi, Corina Orha, Cornelia Ratiu, Florica Manea, Georgeta Burtica
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25220

AbstractThe behaviour of three types of steel, with a variable carbon concentration (from 0.20 to 0.40 %) is studied in medium of ethylene glycol - 10 % methanol - 5 % succinic or adipic acid with water concentration varying between 1 % to 5 %. IR spectroscopy, Xray diffraction and chemical analysis were the methods used for corrosion compounds analysis. The weight losses were measured; also the polarization curves were plotted and the corrosion parameters were established. Based on the obtained...
Autori: Daniel Mareci, Daniel Sutiman, Ioan Iordache, Mircea Teodor Nechita
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25240

AbstractThe health effects caused by air pollutants may range from slight biochemical and physiological changes to difficulty breathing, wheezing, coughing and aggravation of existing respiratory and cardiac conditions. This paper presents an experimental study of air quality in the city of Tg. Jiu, Gorj County, by evaluating the air-floated powders of the PM10 fraction and lead from air. The analysis was performed by measurements in sampling points using the method presented in the European Nor...
Autori: Camelia Capatana, Claudia Maria Simonescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25247

AbstractThe crystallization of ferrierite/ZSM-35 zeolite at 180 Âą 50C in the presence of ethylenediamine as a structure-directing agent from reaction mixtures containing various active NaOH/SiO2 ratios has been studied. X-ray diffraction, scanning electron microscopy, TG/DTG/DSC analysis, nitrogen sorption measurements and temperature-programmed ammonia desorption were used to characterize the ferrierite/ZSM-35 solids. The XRD data reveal that the samples synthesized in optimized conditions are...
Autori: Ioana Droahna, Iuliean Asaftei, Nicolae Bilba
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25251

AbstractAdvanced closing of paper machine circuits results in the accumulation of the dissolved and colloidal substances (DCS) in the process water. At a critical concentration, the DCS are destabilizing even by small variations in paper machine parameters, producing operational and product quality problems. This article presents results of lab experiments simulating the process water recycling in short circuit of paper machine, without and with addition of fixing agents. Tests were performing w...
Autori: Dan Belosinschi, Elena Bobu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25261

AbstractMesoporous Ti-SBA-15 materials have been synthesized up to a Si/Ti ratio of 20 using a two-step pH adjusting method. Low angle X-ray diffraction and diffuse reflectance UV-Vis spectroscopy revealed that the optimal pH value to synthesize highly ordered mesoporous solids having Ti atoms primarily in tetrahedral coordination environments is around 7.5. The nitrogen physisorption and TEM indicated also ordered mesostructures having relatively large surface areas and uniform mesopore size di...
Autori: Adrian Ungureanu, Alexandru Chirieac, Brindusa Dragoi, Cezar Catrinescu, Emil Dumitriu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25263

AbstractZeolites Cs+, Na+-chabazite with SiO2 /Al2O3 ratio of 7 were prepared from gels with molar composition (2.41-2.73)(Cs+ + Na+)2O : (0.02 TPAOH) : Al2O3 : 7.21 SiO2 : (194-204) H2O in static hydrothermal conditions at 108 – 132 0C for 8-21 days. The solids were characterized by X - ray diffraction, scanning electron microscopy, thermal analysis and nitrogen sorption measurements. The nitrogen sorption isotherms at -1960C present a hysteresis loop which is indicative for the existence of ...
Autori: Ionela Droahna, Iuliean Asaftei, Nicolae Bilba
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25266

AbstractThe corrosion resistance of three types of low-carbon steels in water-contaminated mixtures of adipic acid and methanol was investigated. The concentration of water in the organic mixture was progressively raised from 1% to 5%, while the carbon concentration in the steel samples varied from 2% to 4%. Infrared spectroscopy (IR) and X-ray diffraction (XRD) were used to investigate the insoluble corrosion products. Based on the weight losses measurements, on the polarization curves and on t...
Autori: Adrian Cailean, Daniel Mareci, Daniel Sutiman, Mircea Teodor Nechita
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25287

AbstractA new environmentally friendly lignosulfonate-based glue (LSG), which represents the lignin-containing interpolymer complex, has been developed for structuring sandy soils. It has been found that the changes in the LSG composition result in a change in its rheological properties, which are associated with the LSG binding ability and, thereby, have to influence the fractional composition and properties of the created soil aggregates. ...
Autori: Galia Shulga, Julia Brovkina, Juris Ozolinš, Olga Aniskevicha, Talrits Betkers
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25289

AbstractThe aim of this work was to study the content of Fe, Mn, Zn and Pb in the mixtures which contain volatile oil between othercomponents, obtained after the Soxhlet extraction or maceration of the samples (different organs of garden flowers - blue hyacinthand chrysanthemum). The blue hyacinth is a bulbous perennial herb in the Lilliaceae family, grown for its showy and fragrantspringtime flower display. Garden chrysanthemums are tender perennials in the Asteraceae family in double-flowered ...
Autori: , Simona Dobrinas, Viorica Popescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25294

AbstractObservations and data regarding the intense corrosion and deposit phenomena of the carbon steel tube bundle of the heat exchanger are presented. The bundle ensures the cooling of the light fraction C1 - C5 from the top of the distillation column which carries out the removal of pentane and smaller derivates into the RC equipment. Chemical and mineralogical analyses confirm the aggressive action of the fluids flowing through the exchanger. Tests have been done in order to replace the carb...
Autori: Ana-Daniela Georgescu, Lucian Georgescu, Maria Apostolescu, Nicolae Apostolescu, Ovidiu Georgescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25333

Include urmatoarele articole:� Composite membranes with cross-linked matrimid selective layer for gas separation� Determination of organic compounds from different types of coffee by Hplc and Gc-Ecd analysis� An integrated assessment of the suitability of domestic solar still as a viable safe water technology for India� Investigations on the possibility of natural hemp fibers use for Zn(II) ions removal from wastewaters� Removal of acid red 398 dye from aqueous solutions by coagulation...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25340

â€? Photocatalytic properties of titania - fly ash thin filmsâ€? Study of the viscosity of some biodiesel – diesel oil blendsâ€? Aspects refering to technical and leaching properties of the secondary aluminium slags - cement compositesâ€? Studies regarding phenol and 4-chlorophenol sorption by surfactant modified zeolitesâ€? Cu-Ni nanostructured electrocatalysts obtained by electrocodepositionâ€? Molecularly imprinted poly (vinyl alcohol) films for the selective absorption of glycyrrhizinic ac...
Autori: http://www.ecozone.ro/reviste.php?RID=25373

â€? Photocatalytic properties of titania - fly ash thin filmsâ€? Study of the viscosity of some biodiesel – diesel oil blendsâ€? Aspects refering to technical and leaching properties of the secondary aluminium slags - cement compositesâ€? Studies regarding phenol and 4-chlorophenol sorption by surfactant modified zeolitesâ€? Cu-Ni nanostructured electrocatalysts obtained by electrocodepositionâ€? Molecularly imprinted poly (vinyl alcohol) films for the selective absorption of glycyrrhizinic ac...
Autori: http://www.ecozone.ro/reviste.php?RID=25374

Abstract This paper presents the preliminary results of photocatalytic oxidation of humic acid from water using two types of catalysts, i.e., TiO2 and Ag-doped TiO2 modified zeolite (TMZ and Ag-TMZ). TMZ and Ag-TMZ, with zeolite granulation of 315-500 ?Źm was synthesized by sol-gel method, and the morphology and composition of the unmodified/modified zeolite were characterized by BET (Brunauer–Emmet–Teller) method, X-ray Diffraction (XRD), scanning electron microscopy (SEM) and energy dis...
Autori: Cornelia Ratiu, Carmen Lazau, Paula Sfirloaga, Corina Orha, Daniela Sonea, Stefan Novaconi, Florica Manea, Georgeta Burtica, Ioan Grozescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25397

Abstract This paper presents a comparative study of natural and mechanically mixed composting processes of marc resulting as a byproduct during the production of alcohol obtained from fermented fruits. Moisture, temperature, pH values, soluble fraction, total organic carbon, Kjeldahl nitrogen and ash content were monitored for 60 days. During this period the atmospheric temperature varied from 18Â?C to 21Â?C. The composting process could be considered a combination of three stages: mesophilic...
Autori: Anca-Ileana Penu, Daniela Simina Stefan, Mircea Stefan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25407

Abstract Using slag in steel making represents a challenge for road construction industry and decreasing environment interactions also.Steel making slag wit granulations of < 10 mm, which today have not a sure solution, represents the research object. The technological research solutions have aimed reducing CaO free content in these slugs, and reducing slug fraction with granulationof ...
Autori: Florian Zaman, Mirela Gabriela Sohaciu, Ecaterina Matei, Cristian Predescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25439

Abstract In view of the predicted diamond shortage in 2010, a number of innovative processes have been proposed recovering ...
Autori: Frederike Weijmans, Erwin Bakker, Peter Rem
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25441

Abstract Arsenic (As)-contaminated drinking water is a major problem around the world. The removal efficiency depends strongly on the size of Fe3O4 sorbents.Fe3O4 prepared in laboratory is more efficient in the removal of As and is also more easily recovered from column of magnetic separator than the commercial materials. This would be beneficial in a water treatment system because the As-contaminated Fe3O4 could be flushed from the column permitting reuse of the separator system. The dispers...
Autori: Ionel Balcu, Adina Segneanu, Marius Mirica, Mirela Iorga, Catalin Badea, Iuliana Firuta Fitigau
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25456

Abstract Corrosion control, using inhibitors like, polymerisable porphyrins and multifunctional nanocomposites, is extremely useful in many environments. Phosphogypsum is a waste product resulted from the process of obtaining the phosphoric acid and it can be also used as corrosion inhibitor; in a mixture with other coating materials. Two types of modified porphyrin: Na4TFP Ac - dissolved in KOH and H2SO4 and H2TPP - dissolved in benzonitrile, were tested. The structure characterization of pho...
Autori: Ionel Balcu, Adina-Elena Segneanu, Marius Constantin Mirica, Mirela Ioana Iorga, Corina Amalia Macarie, Iuliana Popa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25477

Abstract The paper presents a comparative approach concerning the properties of TiO2 thin layers obtained via spray pyrolysis deposition (SPD) using hydrophilic and hydrophobic polymers as additives. The influences of composition (X-ray diffraction), morphology (Atomic Force Mycroscopy, Contact angle) and optoelectric (electrical conductivity, absorption, band gap and photocurrent) properties on the photocatalytic activity of the layers were studied. ...
Autori: Alexandru Enesca, Luminita Andronic, Anca Duta
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25479

Abstract In order to improve the photo-efficiency of the electronic process as well as the response into the visible part of the spectrum, TiO2 doping with heavy metal (cadmium, cooper and nickel) have been employed. The objectives of this work are: (a) to prepare doped Me(Cd, Cu, Ni) TiO2 by doctor blade (DB) and spray pyrolysis deposition (SPD) techniques, (b) to characterize the catalysts, (c) to study and compare the activity of the Cd-TiO2, Cu-TiO2 and Ni-TiO2 catalysts on methyl orange ...
Autori: Luminita Andronic, Bianca Hristache, Alexandru Enesca, Anca Duta, Maria Visa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25480

Abstract The purpose of this work is to investigate the secondary Al slag (SAS) relating to its technical and environmental properties and, as consequence, to its compatibility with Portland cement matrix. This study may be a contribution to establish of SAS potential valorization as secondary raw material (SRM) in low strength cement matrix composites, as construction products. DRX mineralogical analyses revealed that SAS includes transition alumina compounds, especial boehmite. The hydrati...
Autori: Maria Gheorghe, Nastasia Panait, Romanita Teodorescu, Maria Roman
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25498

Abstract In this work the experimental conditions to synthesize, by direct hydrothermal synthesis, self-bonded pellets of ETS-10 phase containing iron were studied. The following gel composition was used: xNa2O-0.6KF-1.28xHCl-yFe2O3-0.2TiO2-1.49SiO2-39.5H2O with 0.8Â???xÂ???1.4 and 0.015Â???yÂ???0.08. The products obtained were characterized through X-ray diffraction on powders (XRD), thermal analysis (TG, DSC, DTG), scanning electron microscopy (SEM) and microanalysis (EDS). The data obtai...
Autori: Pierantonio De Luca, Danilo Vuono, Monica Filice
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25544

Abstract University campuses can be seen as â€?small cities’ due to their high population (students, professors, employees) and corresponding high traffic flow, which may have a significant impact on both environment and people health. The objective of this work was to analyze particulate matter seasonal trends in the university area of Cosenza (University of Calabria). The relationship between sources emission, meteorological parameters and particle properties was defined. Sampling was co...
Autori: Monica Filice, Pierantonio De Luca, Giuseppe Piero Guido
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25564

Abstract This work describes the preparation of a hydroxyapatite/polyurethane composite membrane and their characteristics. The porous hydroxyapatite/polyurethane composite membranes were made via solvent casting process. The deposited hydroxyapatite layers were investigated by scanning electron microscopy (SEM) and X-ray diffraction (XRD). The data suggest that the method utilized in this work can be applied to obtain deposition of coating of crystalline hydroxyapatite on porous polyurethane...
Autori: Gabriela Ciobanu, Dorina Ignat, Gabriela Carja, Constantin Luca
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25572

Abstract The slags are an important waste and by-products of metallurgical industry. The present paper summarizes results obtained from physical and chemical analyses on metallurgical slag provided from S.C. ?Mittal Steel Galati? S.A. The physical structure and gradation of granulated slag depend on the chemical composition of the slag, its temperature at the time of water quenching, and the method of production. The following mineralogical components were noticed through bypowder X-ray diffr...
Autori: Maria Cioroi, Licuta Nistor Cristea, Igor Creţescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25588

Abstract In the study, the accumulation of secondary metabolites present in Calendula officinalis L. flowers with importance in therapeutics was examined, after the treatment with some substances considered being mutagens. The effect of substances appliedat different concentrations and different times of action was studied, qualitatively and quantitatively, considering various methanol extracts, obtained from the inflorescenses of Calendula officinalis L, which contained polyphenolic fraction...
Autori: Brindusa Robu, Constantin Leonte, Elvira Gile, Roxana Vatavu, Teodor Robu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25598

Abstract The Schiff base N,N??(salicylidene)-methylenediamine, known as Salmen in combination with Cr(III) forms at pH = 4.5 a greenish precipitate, which is stable at room temperature but decomposed on heating. The study of the Infrared spectra, Electron Spin Resonance (ESR), X-ray diffraction and thermogravimetry has pointed out that the precipitation form is a complex, while the molar ratio showed that the combination rate of Cr(III): N,N?-bis(salicylidene)-methylenediamine is 1:1. The new...
Autori: Doina Sibiescu, Ioan Roşca, Irina Spatarescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25619

Temperature distribution in the vacuum directional solidification system influenced seriously on the impurities concentration andmicrostructure in Polycrystalline Silicon. In this study, a numerical model for the transient global heat transfer for directionsolidification process has been developed by the finite element method (FEM). A two-dimension numerical simulation fortemperature distribution of directional solidification process was carried out using software Multi-physics Comsol 3.5a. Ther...
Autori: Guoqiang Lv, Wenhui Ma, Hua Wang, Xiangyang Mei, Kuixian Weihttp://www.ecozone.ro/reviste.php?RID=25671

As one of the very few countries using coal as its dominant energy resources, China has the coal production exceeding one thirds of in the world, added to it are the problems of environmental damages and soil resource destructions result from the solid waste, such as mining waste discharged in the process of coal production and fly ash deserted from the electric power plant etc. In this paper, the mineral ingredient of waste and fly ash was tested by X-ray Diffraction. Meanwhile, the deformation...
Autori: Yanli Huang, Jixiong Zhang, Qiang Zhang, Shoujiang Niehttp://www.ecozone.ro/reviste.php?RID=25677

Chlorine dioxide (ClO2) is widely used as disinfectant in tertiary sewage treatment process. In order to identify the impact of disinfection with ClO2 on treated water quality, secondary effluent pretreated by coagulation was disinfected by ClO2, and the characteristic of dissolved organic matter (DOM) and the biological toxicity of the water before and after disinfection were investigated. The results showed that ClO2 could remove part of DOM and the removal rate of hydrophobic (HO) component b...
Autori: Lihua Cheng, Xuejun Bi, Aihua He, Changqing Liu, Qi Wang, Zuliang Liaohttp://www.ecozone.ro/reviste.php?RID=25692

A series of sodium bentonites as raw material were prepared to the modified inorganic iron-nickel montmorillonites and organic composite montmorillonites. The structural characterization and morphology of the iron-nickel crosslinked modified bentonites were observed by means of IR spectroscopy, X-ray diffraction, scanning electron microscopy. The effects of the amount of bentonites, adsorption time and pH change on the adsorption of Cr(VI) have also been studied. The results indicated that the a...
Autori: Shao Hong, Cao Ninghttp://www.ecozone.ro/reviste.php?RID=25695

Calcium zincate as an active material in Zn/Ni secondary battery has been successfully synthesized by microwave method. The sample was characterized by X-ray diffraction (XRD), thermogravimetric analysis, scanning electron microscope (SEM), chargedischarge test (CT) and cyclic voltammetry (CV) analysis. The results show that the chemical composition of sample is Ca(OH)2¡2Zn(OH)2¡2H2O with regular spherical shapes. The results from CV and CT measurement indicate that the battery has very high d...
Autori: Mengliang Tong, Xuanyan Liuhttp://www.ecozone.ro/reviste.php?RID=25700

The paper analyses the removal efficiency and fluorescence spectroscopic characterization of landfill leachate dissolved organic matter (DOM) fractions in the combined stripping, fenton oxidation, sequence batch reactor, and coagulation process. The high contents of DOM of landfill leachate in each process unit were fractionated into HA, FA, and HyI. The result was the combined process availability for effective removal of DOM fractions. The removal rates for DOM, HA, FA and HyI were 91.9%, 97.1...
Autori: Zhiping Liu, Jin-song Guo, Fang Fanghttp://www.ecozone.ro/reviste.php?RID=25702

Slag-Fly Ash Based cementitious material materials with high volume of fly ash and slag and less cement clinker was prepared, with low water requirement, well fluidity and with high strength, and can be used to the preparation of High Performance Concrete (HPC). When the W/C is 0.36, the 28d compressive strength is 58.93 Mpa, 28d flexural strength is 14.26 Mpa. By XRay diffraction analysis (XRD) and Scanning Electron Microscope (SEM) analysis, the results show that main materials in grinded samp...
Autori: Chenghong Fu, Wen Ni, Hui Wu, Mingyang Tianhttp://www.ecozone.ro/reviste.php?RID=25708

Abstract:The paper presents the influence of different WO3:TiO2 ratios on the photocatalytic and photoelectrolytic properties of the films.The investigations are focused on the morphological (Atomic Force Microscopy, Contact angle), compositional (X-raydiffraction), optoelectric (conductivity, photocurrent) and photocatalytic properties of titanium dioxide films mixed with tungstenoxide. The most important application of these layers is in wastewater purification and hydrogen production using ap...
Autori: Alexandru Enesca
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25743

Abstract:Bioremediation is considered as one of the prominent and cost-effective cleanup technology to treat oily sludge disposals. In the present investigation anaerobic bioremediation of petroleum based oily sludge was studied in a slurry reactor by applying different experimental strategies viz., bioaugmentation, biostimulation and co-substrate addition. Total petroleum hydrocarbons (TPH) present in the oily sludge before and after degradation was extracted using soxhlet extraction procedure....
Autori: Asha Juwarkar, Kuppam Chandrasekhar, Mamilla Prathima Devi, Motakatla Venkateswar Reddy, Ponnapalli Nageswara Sarma, Srinivasula Reddy Venkata Mohan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25794

Abstract:The paper refers at adsorption studies using the maghemite nanoparticles as adsorbent for removal of the hexavalent chromium from aqueous synthetic solutions. Adsorption reached at equilibrium within 10 minutes and was registered as maximum at pH 2.54. The adsorption data were analyzed and fitted by Langmuir isotherm. Investigation methods for characterization of the nanoparticles were X-ray diffraction, scanning and transmission electron microscopy. Also, in order to evaluate the hexav...
Autori: Andra Mihaela Predescu, Andrei Predescu, , Eugeniu Vasile
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25805

An iron(Fe+3) oxide/hydroxide nanoparticles-based agglomerates (AggFe) suspension adsorbent was synthesized for efficient, cost-effective phosphate removal. A strong effect of AggFe concentration and pH level of water containing phosphate on removal efficiency was shown. It was found that phosphate adsorption onto the AggFe suspension may be described by pseudo-secondorder reaction kinetics and the Langmuir isotherm model. The unique adsorption properties of synthesized AggFe adsorbent are demon...
Autori: Grigori Zelmanov, Raphael Semiat
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25829

Biomass is a very interesting natural source to obtain renewable energy as well as chemical products based on a renewable feedstock. Fuel produced from renewable resources is widely regarded as an option to substitute traditional fossil fuels and thus to answer to the adjunct climate debate. For the production of chemical substances from renewable substrates many process options are in investigation worldwide at the moment. However the ecological benefits of these technological options have to b...
Autori: Anton Friedl
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25856

The composite materials based on natural zeolite and undoped and N-doped TiO2, i.e., Z-Na-TiO2 and Z-Na-TiO2-N, were successfully synthesized by solid-state reaction in microwave-assisted hydrothermal conditions. Undoped TiO2 and N-doped TiO2 nanocrystals were previously synthesized by sol-gel method. The X-rays diffraction results of TiO2 nanocrystals indicated that anatase TiO2 is the dominant crystalline type. The composite materials were structural and morphological characterized by X-ray di...
Autori: Cornelia Bandas (Ratiu), Carmen Lazau, Paula Sfirloaga, Florica Manea, Rodica Pode
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25911

The most important argument of this experiment was to demonstrate an increased content of active principles under the influence of some substances (considered in the literature as mutagene), when used in low concentration, do not affect the environment. The purpose of this study was the selection of some treatment variants, which, during the experimentations show the same biosynthetic potential, stabilized or increased. The substances used in the experiment were ethidium bromide at the concentra...
Autori: Constantin Leonte, Marius Zaharia, Roxana Vatavu, Teodor Robu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25867

Newly prepared SnO2-CeO2 catalyst samples used as depollution catalysts were characterized applying low-temperature nitrogen adsorption (BET), X-ray diffraction (XRD), thermo-gravimetry (TG-dTG) and temperature-programmed reduction (TPR) methods. Pure SnO2 has higher surface area (17 m2/g) than the pure CeO2 (8 m2/g). Addition of organic tin oxide precursor to ceria in amount of 5 wt% slightly decreases the surface area of CeO2 (SSn5-Ce= 7 m2/g). The increase of tin oxide content to 10 and 20 wt...
Autori: , Anca Vasile, , Cristian Hornoiu, Jozsef Kovacs, Tatiana Yuzhakova, Veronica Bratan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25875

Fly ash and fly ash based zeolites are inorganics used for improving soil quality. In the current paper, the hydrothermal modification of fly ash was studied. Three methods have been employed for this purpose. The first method involved the use of an autoclave, where synthesis has been performed at a temperature of 120 0C and a treatment time of 4 to 8 hours. Within the second method, the modification of the ash at a temperature of 600 0C by fusion was carried-out. In this method, a mixture of as...
Autori: Corneliu Munteanu, Daniel Bucur, Lacramioara Rusu, Maria Harja, Marinela Barbuta, Ramona Carla Ciocinta
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25885

AbstractIn this paper, we report a study on structural evolution, magnetic susceptibility and arsenic content of colloidal pyrite fromXinqiao deposits in Tongling, Anhui Province, China. The pyrite was treated under N2 atmosphere and charaterized with X-raypowder diffraction (XRD), field emission scanning electron microscopy (FE-SEM), magnetic susceptibility analysis, and atomicfluorescence spectroscopy (AFS). We observed that heating of colloidal pyrite in N2 atomosphere did not change the crys...
Autori: Dong Chen, Ping Li, Tianhu Chen, Xiao Zhu, Yadan Shi, Yan Yang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25951

AbstractThe preliminary assessment of a cost-effective flow-sheet for the production of biodiesel from microalgae lipid fraction wascarried out. The study was based on approximated cost-estimation methods integrated with the simulation software Aspen PlusŽ.Several scenarios were investigated to compare costs regarding the main steps of the biodiesel production process. Ranges ofinput variables from downstream literature and experimental data were used to simulate the sections that define concret...
Autori: Antonio Marzocchella, Giuseppe Olivieri, Piero Salatino, Teresa Guida
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25973

AbstractIn this paper the synthesis, characterization and testing of composite material based on multi-wall carbon nanotubes and silverdopednatural zeolite (MWCNT-ZAg) has been investigated for humic acid (HA) adsorption. The surface characterization of thecomposite material has been investigated by X-ray diffraction (XRD) and scanning electron microscopy (SEM/ EDX) analysis.The Langmuir and Dubinin-Radushkevich (D-R) models fitted the best experimental data informing that adsorption process ofH...
Autori: Aniela Pop, Corina Orha, Florica Manea, Virgil Tiponut
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26023

AbstractMultifunctional materials based on iron substituted anionic clays and their derived mixed oxides owning specific porousproperties and textural characteristics are synthesized, characterized and tested as photocatalysts in the process of the azo-dyesdegradation from aqueous solutions. The features of X-ray diffraction patterns point out the modification of the lattice parameterswhen Fe3+ is substituted Al3+ in the brucite like layer. N2 adsorption-desorption analysis reveals specific poro...
Autori: Carmen Gherasim, Gabriela Carjă, Magda Puşcaşu, Mihaela Bîrsanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26024

AbstractA comparative study regarding the shape, dimension and bactericidal activity of the undoped and Ag-doped TiO2 nanocrystalswas achieved. In this way, two hydrothermal methods, classical hydrothermal and microwave-assisted hydrothermal, was usedfor nanoparticles synthesis. The obtained materials were investigated by X-ray diffraction, DRUV-VIS spectroscopy, BET andSEM/EDX analysis. Antibacterial activity of undoped and Ag-doped TiO2 materials was tested on real water from Bega River.The be...
Autori: Carmen Lazau, Corina Misca, Corina Orha, Cornelia Bandas, Sorin Olariu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26034

AbstractWater quality is an inportant concern for the ecosystem state from a particular region. Since the continuous urban and economicdevelopment induces a negative impact on entire hydrological cycle, this study investigates the water quality of a Romanian lake,located in the Surduc area - Timis County. This perimeter has undergone significant economic development in the past twodecades due to increased tourism potential and the number of holiday residences.We proposed hybrid materias for the ...
Autori: Adina-Elena Segneanu, Cornelia Bandas, Florentina Cziple, Ioan Grozescu, Paula Sfîrloagă, Titus Slavici
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26040

AbstractA new approach to environmental protection management is the aerobic microbial digestion of food industry wastewaters byusing those waters as substrate, while the pollutants contained work also as oxygen-vectors. In biotechnology, oxygen masstransfer is a key parameter involved in the design and operation of mixing–sparging bioreactors and it can be analyzed by meansof the oxygen mass transfer coefficient (kLa). The influence of a second liquid phase with higher oxygen affinity (in this ...
Autori: Elena Folescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26097

The book edited by Haibo Xie and NicholasGathergood focuses on one of the most importantscientific issues of the 21 century which is thereplacing fossil fuel with sustainable alternatives suchas biomass. Fossil fuels are conventional rawmaterials for many industrial sectors includingchemical and energy production. Usage of fossil fuelis limited by their availability, price and carbonfootprint. Biomass is a renewable resource globallyavailable, cheaper and carbon sequestering. Step bystep shiftin...
Autori: Adrian Catalin Puitel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26101

Abstract Waste recycling represents a very significant issue for the protection of our environment. Large waste quantities (slag and ashes) are products of the coal extraction industry and its subsequent combustion in thermal power stations. The possibilities of obtaining crystallized glasses in the CaO-Al2O3-Fe2O3-SiO2 system by introducing in the raw materials mixture ashes from Mintia Deva thermal power station have been studied. The physical and chemical characterization of the...
Autori: Firuţa Goga
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26121

AbstractThe reuse of a wastewater treatment system was investigated using intermittent media infiltration (IMI) to evaluate the fecalcoliform (FC) removal efficiency with natural zeolite containing clinoptilolite from the state of San Luis Potosí, Mexico and itszinc-modified form (Zeo-Zn). The municipal wastewater, which was from Saltillo, Coahuila, Mexico, was treated for FC analysisfor four months. The physicochemical properties of zeolite were analyzed, and their behavior as filter media for ...
Autori: Sasirot Khamkure
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26212

AbstractIn 1979, the Gheshlagh river continuum was affected by the construction of Gheshlagh dam. More than three decades afterpresence and operation of this dam, there is a necessity to evaluate water quality in Gheshlagh reservoir. Therefore, water quality data was determined monthly from October 2008 to September 2009, to evaluate the impact of Gheshlagh dam presence and operation on the reservoir’s water quality. Eight parameters were analyzed (dissolved oxygen, biological oxygen demand,chem...
Autori: Fariba Rezaei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26225

AbstractWashing black aluminum (Al) slag to obtain soluble salts is an important stage of the smelting slag treatment at technologicalprocess. This process is used to recover Al as a coagulant for water purification. This research aims at establishing the optimalconditions for washing (e.g. temperature (T), solid: liquid ratio (S : L), time, the recirculation waters in the system). The goal ofresearch was to determine: a) the removal with maximum efficiency of the soluble salts from black Al sla...
Autori: Romanita Teodorescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26243

AbstractThe intercalation of 2,6-dichlorobenzonitrile (DBN) into the NiMgAlLDH, CuMgAlLDH and MgAlLDH layered doublehydroxides was carried out using the calcination-rehydration reaction using NiMgAl, CuMgAl and MgAl oxide precursors,obtained by calcination at 550oC. X-ray diffraction (XRD), elemental analysis, infrared spectroscopy (FTIR) andthermogravimetric analysis (TG-DTG) confirmed that DBN molecules were successfully intercalated into the interlayer spaces ofLDHs. The resulting solid produ...
Autori: Mihaela Silion
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26244

AbstractInvestigations on thermochemical transformation of asbestos fibers followed by computer aided image analysis are presented.Asbestos Containing Wastes (ACW), notably asbestos-cement, were characterized before and after microwave heating withadditives aimed at reacting with and transforming asbestos fibers. Microprobe analysis helped determine the chemicalcompositions. X ray diffraction (XRD) was used to confirm decomposition of asbestos fibers during microwave heating. Electronparamagneti...
Autori: Yan Yvon
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26256

AbstractThis paper presents the results of the removal of arsenite and arsenate ions from an aqueous solution using Fenton modified solid waste vegetable oil industry (SWVOI). Several factors (such as pH, contact time and Fe2+/H2O2 ratio, initial arsenic ion concentration and adsorbent concentration) that affect the arsenic ion adsorption on the SWVOI adsorbent material were investigated. The sorption characteristics of the adsorbent material before modification were also studied and compared wi...
Autori: Hoda Amiri, Mehdi Ahmadi, Nemat Jaafarzadeh, Susana Silva Martínez
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26290

AbstractThe monitored natural attenuation (MNA) of groundwater contamination is in many cases considered to be a cost-effective andappropriate strategy to manage the remediation of contaminated aquifers. A prerequisite for the public acceptance of such NAremediationapproaches is that the efficiency of the presumed NA-processes should be proven. This proof must be based on anextensive hydrogeological and in-situ characterization of the ongoing aquifer processes. Additional investigations of aquif...
Autori: Achim Möller, Anja Berning, Anne Berghoff, Bernd Mahro, Christoph Wortmann
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26312

AbstractThe distribution and fractionation of nine heavy metals (Cr, Co, Ni, Cu, Cd, Zn, V, Pb and As) in the sediments of Lake Chaohu,a shallow eutrophic lake, were investigated using the BCR sequential extraction procedure. The level of pollution attributed tothese nine heavy metals was evaluated employing the potential ecological risk index (RI) and geoaccumulation index (Igeo). Metalconcentrations in sediments ranged from 65.00~104.00 for Cr, 14.50~21.70 for Co, 28.50~50.90 for Ni, 25.40~51....
Autori: Beidou Xi, Fengyu Zan, Guangchao Zhao, Jing Su, Kevin M. Yeager, Shouliang Huo, Xiujuan Yu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26321

AbstractThe main objective of the current research is to determine the content of heavy metals from the Bistrita river banks, respectivelyupstream of Bacau city, Romania, in Bogdan Voda area, and downstream of Bacau city. Because of their bio-accumulationtendency heavy metals can generate a negative impact on soil, as well as on certain physiological and biochemical indicators ofplants and animals metabolism. The selection of sampling points (upstream and downstream of Bacau city) took intoconsi...
Autori: Cristian Radu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26436

AbstractThe washing method for uranium contaminated soils using three different reagents was investigated. Experimental data havebeen obtained for four types of soils, which have been characterized in terms of particle size distribution, as well as structure andchemical composition. Thus, the decontamination degree for each type of soil and reagent respectively has been measured.Subsequently, the decontamination process has been simulated using an artificial neural network. Based on this neural ...
Autori: Alexandru Woinaroschy
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26451

AbstractAs air quality becomes increasingly deteriorated in world-wide cities, air quality monitoring has extended beyond the criteriapollutants (CO, SO2, NOx, O3 and PM) in order to include several toxic air pollutants such as volatile organic compounds(VOCs). In the present study it was investigated the presence of 29 VOCs and PM including PM2.5, PM2.5-10 and PM>10 fractions,in an urban area from Romania. The total VOCs was higher in the urban area (176.72 - 192.54 μg/m3) than in the r...
Autori: Carmen Roba
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26504

AbstractAnalysis and monitoring of arsenic is still a challenging analytical task. Due to its complex behaviour (different forms of arsenicthat can be present depending on pH and oxidation states of arsenic) as well as demanding analytical procedures and instrumentaltools for control of arsenic concentration in drinking water which is set to 10 μg L–1, there are still some open questions andissues when arsenic is the scientific topic. In this paper the idea was to use a multivariate statist...
Autori: Vladana N. Rajakovic-Ognjanovic
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26506

AbstractNano-Ag electrodeposited on carbon nanotubes-epoxy and carbon nanofibers-epoxy composites electrode materials as Ag-CNTand Ag-CNF electrodes were tested for simultaneous detection of arsenic (III) and lead (II) from aqueous solution. Theelectrochemical behaviour of As(III) and Pb(II) on both composite electrode offered useful detection information and Ag-CNFexhibited better electroanalytical performance. The detection scheme using Ag-CNF for simultaneous detection of As(III) andPb(II) wa...
Autori: Anamaria Baciu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26511

AbstractGreywater (GW) has attracted global attention as an alternative water source over the last few decades. GW treatment andreliable reuse require the overall qualitative characterization of samples from different sources. This paper represents aninvestigation of household-generated GW in the Northern Great Plain Region of Hungary. Modern and reliable analyticaltechniques and instruments (ion chromatography, microwave plasma atomic emission spectrometry, Zetasizer Nano Z analysis,etc.) were ...
Autori: Ildiko Bodnar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26528

AbstractThe primary objective of this research was to develop safe, programmable and cost-effective technologies of plantlet productionfrom the seeds of undomesticated American populations of Virgina fanpetals (Sida hermphrodita RUSBY). During our seedpriming treatment experiments, approximately 40% of the Virginia fanpetals seeds that were high-quality, infection-free,normally imbibing and germinating seeds. Our spring propagation tray experiments indicated that the spring large-scale trayplant...
Autori: Erika Kurucz
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26545

AbstractThe adsorption potential of 10 wt.% COOH/TUD-1 material for removing Cd2+ from aqueous solutions was investigated via thebatch technique, and the effects of pH, temperature and contact time were studied. Experimental data showed that the maximumCd2+ adsorption, 90%, occurred at pH 6. The adsorption equilibrium was reached within 35 min for 10 wt.% COOH/TUD-1. Theadsorption mechanism was investigated in terms of its thermodynamics and kinetics. The adsorption data were fitted using theLan...
Autori: Nabila Bensacia
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26558

AbstractHeavy metals in sludge have been one of the limiting factors for sludge reclamation, and therefore the changes of heavy metalsduring sludge treatment process should be concerned. This study investigated the detailed profile of changes of seven typicalheavy metals (As, Cd, Cr, Cu, Ni, Pb, and Hg) in the activated sludge during ultrasonic treatment process. The influences ofsonication time and ultrasonic power density were studied. Results showed that heavy metals in sludge were released i...
Autori: Tian Wan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26563

AbstractThe incorporation of phosphorus (P) into sediments and the changes in its bioavailability under intermittent P input and sedimentresuspension conditions were investigated via laboratory experiments. The sediments were disturbed daily for 10 min and thenallowed to settle for 1430 min after each disturbance to simulate the intermittent sediment resuspension conditions. The removalof soluble reactive P from the overlying water under sediment resuspension was greater than that under static c...
Autori: Li Dapeng
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26567

AbstractThe general aim of this paper is to demonstrate the sustainable management of a broad spectrum of wastes (livestock, industrial,agri-food, agricultural and non-recyclable fraction proceeding from waste treatment plants) in an integrated plant. Thetechnological development and practical application of the “Mixed Plant” concept is used to achieve this objective. In order tovalorize in a joint form all the above-mentioned categories of waste, two different processes have been integrated. Th...
Autori: Dolores Hidalgo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26579

Abstract Soil organic carbon is one of the key substrates affecting methane emissions in paddy fields. However, not all soil organic carbon forms methane. This study therefore involved comparative analysis of the methanogenesis of different organic carbon sources (rice straw, chicken manure and pig manure) in paddy field soils. The results indicated that whereas methane emissions from the pig manure treatment (PM) were not significantly different to those associated with the application of c...
Autori: Jiamei Wu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26637

Abstract The influence of exogenous form of heavy metals intake on their transformation in the soil is determined during model experiments. Distinctions in quantity of extracted mobile compounds of heavy metals in the soil depending on a form of addition various connections of Cu and Zn are established. The smallest mobility of Cu and Zn at addition of heavy metal oxides is observed. It is established that Cu accumulates mainly in the fraction connected with organic matter; Zn accumulates in...
Autori: Tatiana M. Minkina
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26662

Abstract Magnetic contamination is considered more and more as a challenging issue related to biosphere pollution with magnetic materials originating in natural and artificial sources (volcanic eruptions and respectively industrial activities that contributed to iron and other metal compounds spreading in air, water and soil). Aiming to study the impact of magnetic metal ions such as iron and cobalt on the metabolism of some environmental microorganisms, in this paper an experimental simulat...
Autori: Lacramioara Oprica
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26675

Abstract The bismuth oxide (Bi2O3) nanoparticles are easily synthesized from a solution of bismuth nitrate pentahydrate (Bi(NO3)3·5H2O) in ethylene glycol by a hydrolysis solvothermal route at temperatures of 120-150C. X-ray diffraction, scanning electron microscopy and UV-visible diffuse reflectance spectroscopy are used to characterize the products. The results show that the reaction temperature, the reaction duration and the initial solution concentration play important rol...
Autori: Xiaowen Luan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26689

Abstract Individual exposure to particulate matter (PM) fractions is mainly determined by indoor source characteristics and personal activity patterns. This paper discusses experimental results obtained through the analysis of individual exposure of women to PM10 and PM2.5. To this purpose, 15 volunteers of different ages and lifestyles living/working in Ceccano (Italy) were selected and their exposures to PM10 and PM2.5 were measured through a handheld photometer. They also filled out a tim...
Autori: Giorgio Buonanno
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26703

Abstract In this study we report the preparation and evaluation of the antimicrobial activity of a new hybrid material based on chitosan (CH), magnetite (Fe3O4) and phytocomponents from the Eugenia carryophyllata aqueous extract (AE). CH/Fe3O4 was prepared by chemical precipitation of Fe2+ and Fe3+ ions in aqueous solution of sodium hydroxide and CH. E. carryophyllata’s dried buds were hydrodistilled under microwave conditions. The AE was separated in three equal parts, one for the chl...
Autori: Ion Anghel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26707

Abstract Planktonic algal samples were collected from lakes with different salinity (Salt Lake Brăila, Amara Lake, Fundata Lake, Techirghiol Lake and Black Lake-Sovata), in which mud used in balneary therapy is formed. A total of 189 species were recorded: 35 Cyanobacteria, 10 Euglenophyceae, 96 Bacillariophyceae, 33 Chlorophyceae, 3 Chrysophyceae, 2 Cryptophyceae, 1 Xantophyceae and 9 Dinophyceae. The highest number of phytoplankton species was recorded in Techirghiol lake (127 species...
Autori: Liana Gheorghievici
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26719

Abstract Particle size distribution is one of the most influential factors of most soil physical and even some soil chemical characteristics. As modern measurement techniques are being introduced, the need for comparing new methods with older methodologies arises because comparability means data continuity. Here, three institutes conducted a comparison of particle size measurement among the laser, areometer and pipette techniques. The purpose of the comparison was to a) discover any differen...
Autori: Csaba Centeri
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26733

Abstract An experimental study of mixing in autoclave vessel equipped with an anchor impeller was performed on the sludge proceeding from the treatment of mixed municipal and industrial wastewater. This unit operation is part of a process for the recovery of sludge. The mathematical modelling of the mixing was done having in view the scaling-up of this process. The mathematical model allows the calculation of the mixing power N as a function of the impeller diameter d, the vessel diameter D,...
Autori: Ancaelena Eliza Sterpu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26744

Abstract The aim of this paper is to determine the heat of combustion of plastic wastes resulted from municipal solid waste, automotive shredder facility waste and building and construction waste. The plastic wastes have been separated by flotation technique using as flotation media: water, ethanol, their mixtures and magnetic fluid. Resulted fractions have been analyzed aiming to determine the most effective fraction from the heat of combustion point of view. The obtained results have been ...
Autori: Liviu Costiuc
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26750

Abstract In this study, the comparative photocatalytic activities of undoped and N-doped TiO2 anatase nanocrystals towards the degradation of Reactive Yellow 125 (RY125) azo reactive dye in aqueous solutions under UV and VIS irradiation ranges were investigated. Both nanocrystals prepared by a fast-hydrothermal method using titanium isopropoxide as precursor were characterized morpho-structurally by X-ray diffraction, SEM/EDX analysis and BET measurements. Also, optical features of the nano...
Autori: Corina Orha
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26757

Abstract Waste management does not try to dispose waste anymore but is searching for the best solution to manage valuable and scarce resources and reduce the negative impact on the environment. Preoccupation in Germany with regard to optimization of waste recuperation and valorization increases and separate collection systems for different waste fractions are taken into consideration. Within this study a pilot project was set up and its results are presented below. The investigation evaluate...
Autori: Mihaela Berechet
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26758

Abstract This study focused on the fate of the most representative metals in urban wastewater treatment by the conventional activated sludge process. The research analyzed: distribution between soluble and particulate fraction in the different treatment stages, removal efficiencies as related to partitioning, and metal behavior during rainfall events. A mass balance approach allowed evaluating the behavior of the metals, migration between phases and final fate, in order to investigate metal ...
Autori: Giancarlo Cecchini
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26773

Abstract Thermophilic anaerobic digestion is a suitable technology to treat agricultural waste because of its higher biogas production, hygienisation effect and solids removal efficiency. Although these benefits, poor effluent quality and instability are encountered in some cases. The anaerobic co-digestion of winery waste and waste activated sludge at 55°C, operating at 23 days HRT and with an organic loading rate of 3.2 kg COD/m3d, was characterized by accumulation of volatile fatty ac...
Autori: Cinzia Da Ros
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26775

Abstract The increasing diffusion of Hi-tech complex products has raised the attention of scientific community towards their End of Life (EoL) treatment, both in terms of assuring an appropriate disposal, to avoid the dispersion of harmful substances, and at the aim of their exploitation as valuable sources of raw materials. Within this study an integrated approach for waste electrical and electronic equipment (WEEE) end of life treatment is proposed based on the integration of hydrometallur...
Autori: Claudia Brunori
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26777

Abstract The recovery of raw materials from waste represents a sustainable growth opportunity for those countries with limited mineral resources availability. A case study for an integrated approach to recover raw materials from spent fluorescent lamps is presented, with the aim of improving the current treatments which are only able to recover the glass fraction. In particular a hydrometallurgical process was developed to obtain valuable metals such antimony, copper, and rare earths (yttriu...
Autori: Roberta De Carolis
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26782

Abstract The amount of collected Waste Electrical and Electronic Equipment (WEEE) in Europe is growing about 7 wt.-% per year (2007- 2012). It contains a number of economically relevant base, precious and high-tech metals. However, only a limited number of these metals can be recovered by currently applied recycling processes. Especially high-tech metals like gallium, germanium and tantalum get lost during the treatment of WEEE. The pyrolysis technology allows an accumulation of these metals...
Autori: Peter Hense
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26785

Abstract Drinking of arsenic contaminated waters has been reported adversely affect our health even at a concentration level as low as 10 g/L, therefore the availability of a reliable and cheap, and an environmentally arsenic detection kit is really indispensable. Although simple field test kits have been developed, most of them use toxic mercuric salt as a color-generating reagent for arsenic detection. Hence this study was conducted to develop a simple, cost effective, and environm...
Autori: Keat Khim Ong
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26819

Abstract The amount of bottom ash produced in Italy from municipal solid waste incinerators is estimated at over a million tons per year. Up to now, it has almost all been disposed of in landfills. Therefore, large profit margins, from both the economic and environmental standpoint, can be expected from the recovery of this material, or at least from a fraction of it. In this study, a rapid procedure for the recovery of different bottom ash fractions based on mechanical sorting and aging was...
Autori: Ivano Vassura
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26853

Abstract The adsorption of phosphorus (P) on sediment plays a significant role in phosphorus transport in aquatic systems. This research examined the effect of the main components of sediments (including iron (Fe), manganese (Mn) oxides and organic matter (OM)) on P adsorption and to evaluate their relative contribution with different sediment particle sizes. The sediments were separated into four particle-size fractions: 0-30 μm, 30-62 μm, 62-90 μm, and 90-125 μm, and then selec...
Autori: Yang Xiao
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26873

Abstract Urban areas represent the main zones of anthropogenic emissions and, at the same time, includes the largest number of population exposed to air pollution. Data related to traffic hot spots locations in Sibiu urban areas are presented and discussed in this paper. It is important to assess the impact of changing climate conditions and concentration of pollutants, these aspects are of special interest because of high and increasing population of urban regions exposed to consequences of...
Autori: Valentin Petrescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26887

Abstract Waste management in Romania, in particular in Cluj-Napoca city, needs major improvements. By analyzing the results and implementation of waste composition studies which have been performed in different countries, it can be easily noticed that they can play a very important role in the planning stage of waste management, but also in the monitoring and evaluation of the process. Moreover, waste composition studies are an integrated part of waste management planning in developed countr...
Autori: Ioana Nicoleta Pop
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26888

In this work, coagulation features and characteristics of dissolved organic matter (DOM) in combined sewer overflow (CSO) wastewater were investigated. Ferric chloride (FeCl3) and polyaluminum chloride (PAC) were employed in the coagulation process. Results showed that both FeCl3 and PAC are effective in removing turbidity and total phosphorus (TP). Removal efficiencies were all above 90% when dosages were reasonable. Chemical oxygen demand (COD) removal efficiency was between 60% and 70%. T...
Autori: Wei-gang Wang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26931

Ferric sulfate and aluminum sulfate were applied to stabilize the available arsenic in solid waste residue (SWR) from the organic arsenic industry, previously pretreated by the semi-solid Fenton process. NaOH, Ca(OH)2, and MgO were introduced to adjust the matrix pH. Toxicity characteristic leaching procedure (TCLP), synthetic precipitation leaching procedure (SPLP), and sequential extraction procedure (SEP) were carried out to evaluate the effect and difference on the fixation treatments of ...
Autori: Li-Fang Hu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26956

This paper studies, in lab scale, the possibility of removing a rich-in-pollutant soil fraction using flotation, with the clean fraction been restored to its natural condition. The tests were carried out in a conventional flotation cell with mechanical agitation. Artificially polluted soil was used throughout this study by mixing soil with diesel fuel. The effect of the following flotation factors was studied: pulp pH, collector type and quantity, conditioning and flotation time, initial soil...
Autori: Nickolaos Georgiou
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26960

In past ten years area of green technologies and materials was the most growing industry sector in the world. It is related with global warming, air pollution and energy saving. Building sector intensively increased air pollution and is related with high energy consumptions. The use of renewable or recyclable materials can reduce these problems. In current work, thermal insulating materials from hemp shives and corn starch were investigated. Structures of various shives fractions were analyz...
Autori: Giedrius Balčiūnas
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26992

Fly ash is the major residue produced during the combustion of coal. Research has been carried out to recover silica and alumina from fly ashes collected from different thermal power plants in India. Silica and alumina from the fly ash were recovered and the recovered products were subjected to X-ray diffraction, X-ray fluorescence and Inductively Coupled Plasma-Optical Emission Spectroscopy analyses to estimate the silica and alumina content. Total recovered silica content in the samples was...
Autori: Ruth Sherly Endluri
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27007

The arsenic removal from aqueous medium was investigated through adsorption by employing finely powdered bark of Pinus roxburghii Sarg. The batch mode laboratory scale experiments were conducted to investigate the removal efficiency of Pinus bark against total arsenic and the effect of pH, contact time, adsorbent dose and initial adsorbate concentration on adsorption to optimize the process. Langmuir and Freundlich isotherms were used to validate the adsorption data and respective constants w...
Autori: Syed Hasnain Shah
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27013

This paper aims to establish the capacity removal of hexavalent chromium [Cr(VI)] from wastewaters using a TiO2 – Fe3O4 based nanocomposite. Latest researches in the field point adsorption as a better option for removal of heavy metal ions from waters, this method being more efficient and cost effective, in comparison with other advanced methods like reverse osmosis, ion exchange, nanofiltration, etc. Based on this information, the goal of this work had as purpose the obtaining, charact...
Autori: Andra Predescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27025

The investigation of bottom sediments in oxbow lakes was conducted in the free-flowing, meandering section of the Łyna River in N Poland. Seven oxbow lakes, differed by a degree of hydrological connectivity with the river channel, were chosen for the present study. In samples taken from 21 sediment profiles, particle size distribution, pH, bulk density, CaCO3, organic matter, total organic carbon as well as total forms of N, P, K, Ca, Na, Mg, Mn and Fe were determined. The gradient of de...
Autori: Szymon Kobus
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27052

The paper deals with the amounts of total and plant available forms of heavy metals (Pb, Cr and Cu) and relation between soil properties in three catenas in postglacial area of the Łyna River valley, NE Poland. The results were presented on the background of four geochemical landscapes distinguished within the study area: eluvial or trans-eluvial, eluvial accumulative, trans-superaqual and super-aqual. The average total content of heavy metals amounted to: Pb – 14.05 mg kg-1 d.m., ...
Autori: Paweł Sowiński
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27058

Triton X-100 (TX100) and Tween 80 (TW80) were used to study the decontamination of polycyclic aromatic hydrocarbons (PAHs) in the bulk and different size fractions of soil samples from a former coke oven plant. The effects of PAH ring number, initial concentration and soil total organic carbon (TOC)/black carbon (BC) contents on PAH removal efficiencies were analyzed. Surfactant washing for the bulk sample showed clear relation between the removal efficiency and PAH ring number. When the sur...
Autori: Helian Li
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27093

Iron humate (IH) produced as a waste by-product during the industrial manufacture of humic substances from young brown coal was tested as a new cost-effective sorbent for the removal of inorganic arsenic from waters. Its removal efficiency was compared with that of two other non-conventional sorbents – magnetite and oxihumolite (weathered brown coal). Magnetite and IH have been found to be effective in removing both forms of inorganic arsenic (arsenite and arsenate) from aqueous solutio...
Autori: Pavel Janoš
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27098

This paper analyzes and compares the effects of bioremediation on total petroleum hydrocarbon (TPH) degradation using composting techniques as well as biostimulation and bioaugmentation approaches. Compost and sludge were added as organic amendments with the dual purpose of providing both nutrients and microorganisms to the contaminated soil. In addition, the effect of inoculation with white-rot fungus Trametes versicolor was assessed. Two different types of soils were considered: a poor soi...
Autori: Juliana Abraham
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27101

This study proposes a modified fractional fuzzy simulation (MFFS) method to predict the toluene and oxygen concentrations in aquifers under microbial attenuation conditions. The method integrates the modeling of groundwater flow contaminant transport and fuzzy parameters analysis within a general framework. Compared to conventional fractional fuzzy simulation (FFS), decreased interior points of fuzzy parameters need to be used, thus reducing the simulation time. The method is applied to an a...
Autori: Li He
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27106

Biological control relying on soil microorganisms may offer feasible and sustainable perspectives in many agrosystems for management of soil pests such as root-knot nematodes (RKNs, Meloidogyne spp.). The rhizosphere environment shows a complex of soil microbial communities, including beneficial organisms such as specialized bacterial pathogens and/or of rhizosphere fungi. New advanced technologies like Next Generation Sequencing (NGS) may enlarge our knowledge about the biodiversity and rol...
Autori: Aurelio Ciancio
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27109

In Palestine, the energy situation is unique compared to other Middle Eastern Countries, as there are technical and political challenges for transporting, storing, importing and exporting energy. Actually, energy import from Israel meets the major share of Palestinian energy needs. Palestinian reliance on Israel concerning its energy supply is an issue due to the political situation. Furthermore, from an environmental point of view, Israel predominantly relies on fossil fuels for its own elec...
Autori: Jacopo Bacenetti
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27120

Rapeseed meal (RM) is an abundant and cheap by-product of oil extraction process. RM is a rich source of nitrogen, carbon, and minerals. Thanks to these features, RM has a striking potential for eco-friendly production of high value products in biotechnological processes. In this study, the possibility of using a low-cost medium based on the water soluble fraction of RM for laccase production by the fungus Pleurotus ostreatus has been evaluated and compared with the use of synthetic complex ...
Autori: Lucia Guarino
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27129

Animal manure is widely used as organic fertilizer for crops. However, high concentrations of heavy metals in animal manure are of great concern. In this study, we found that chicken and pig manure compost contain high concentrations of arsenic (As), cadmium (Cd), copper (Cu) and zinc (Zn), and the concentrations of these heavy metals in the pig manure were higher than those in the chicken manure. Chicken or pig manure compost fertilization elevated the concentrations of these heavy metals in th...
Autori: Guilan Duan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27155

The effectiveness of thermal insulation materials mostly depends on their thermal conductivity. The low thermal conductivity is predetermined by density, structure, moisture content and temperature of material and, considerably less, by other indices. Loosefill cellulose insulation is allocated to the group of materials, the density of which fluctuates within large limits. This property is related not only to application of cellulose wool in different constructions, but also to technological ...
Autori: Sigitas Vėjelis
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27165

The adsorption of tartrazine from aqueous solution was evaluated using an iron (III) modified zeolitic tuff. The adsorbent was characterized by scanning electron microscopy and X-ray power diffraction; the modification process does not affect the crystalline structure of the zeolitic tuff. Sorption kinetic, isotherms, dose and pH effects were determined and the adsorption behavior was analyzed. The sorption equilibrium was reached in 72 hours, the adsorption capacity determined by the Langmuir m...
Autori: Adrián Alcántara-Cobos
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27182

Hesperaloe funifera was studied as a new raw material for paper manufacturing and lignin recovery. An experimental design was carried out to improve the quality of the obtained pulp varying the process temperature (155, 170 and 185 ºC), time reaction (20, 40 and 60 minutes) and soda concentration (5, 10 and 15 %). All experiments were carried out with 1% anthraquinone. Lignin content, holocellulose content, α-cellulose, viscosity, Kappa number and drainability were determined in the d...
Autori: MŞ Ángeles de Andrés
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27185

This study was carried out to (1) investigate the potential of in-vessel solid-state anaerobic acidogenic co-digestion of high solids containing substrates, namely organic fraction of municipal solid waste (OFMSW) and cow manure and (2) examine the feasibility of using leaching bed reactors (LBR) for hydrolysis/liquefaction and acidification of OFMSW and cow manure mixtures for maximum total volatile fatty acid (VFA) and alcohol production. Results indicated that hydrolysis efficiency of 20-25% ...
Autori: Tuba H. Erguder
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27186

Waste from a cola beverage industry containing high concentration of phosphorus (P) was treated by the struvite precipitation method. The influence of excess of ammonia and order of reagent addition were evaluated as independent variables on the removal and recovery of phosphorus from cola beverage waste. It was removed about 95% of P of the sample in a short reaction time. The precipitated crystals were identified and analyzed by X-ray Diffraction (XRD), infra-red spectroscopy (IR) and surface ...
Autori: Wilson Roberto Barreto dos Santos
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27188

Catalysts based on nanocrystalline Mg-Zn ferrites supported on commercial alumina were prepared by in situ sol-gel auto-combustion technique. The as-obtained materials were characterized using Fourier Transform Infrared Spectroscopy (FT-IR), X-ray diffraction (XRD), atomic force microscopy (AFM) and Brunauer-Emmett-Teller (BET) specific surface area measurement. These materials were tested as catalysts for hydrogen peroxide decomposition and phenol oxidation reactions. The catalytic activity of ...
Autori: Tamara Slatineanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27192

Adsorption equilibrium, kinetic and dynamic studies were done for removal of zinc (II) from aqueous solutions using alunite ore. The alunite sample was characterized by using X-ray fluorescence (XRF), optical microscopy, X-ray diffraction (XRD), scanning electron microscopy (SEM), Brunauer–Emmett–Teller (BET) porosimetry, differential thermal (DTA), and Thermogravimetric (TG) analyses. The batch equilibrium adsorption data of zinc (II) ions onto alunite particles were applied to some...
Autori: Hoda Arabyarmohammadi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27216

The capability of ornamental rocks solid waste (ORSW) as a low-cost sorbent was investigated in order to remove As(V) and Mn(II) from aqueous solution. Physical-chemical characterization analyses of the raw material presented albite and quartz as the main minerals. The solid waste presents low surface area (209.70 m2/g). The Langmuir, Freundlich, Sips (Langmuir-Freundlich), Redlich-Petersen and Tóth models were used to analyze sorption phenomena. The maximum sorption capability from the e...
Autori: Fernando Jorge Santos Oliveira
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27246

Many industrial complexes in Korea have produced a variety of potential toxic chemicals during manufacturing processes and activities by air emissions, effluents, or solid wastes over the past few decades. In this study, arsenic levels in air, soil, and water near an industrial complex were determined. Human health risk assessment for arsenic was conducted based on the levels and potential exposure pathways in a multimedia environment (air, soil, and water). The point estimate of incremental can...
Autori: Yong-Chul Jang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27249

Different bioleaching processes were applied to mining wastes deposited in the highly polluted post-industrial region - Lower Silesia in Poland. The chemical characterization of the wastes before and after bioleaching processes was performed. The characterisation was based on the distribution of selected elements (Fe, Mn, As, Co, Cr, Cu and Ni) between operationally-defined phases. The phases were defined using a six-step extraction procedure optimised according to the properties of the studie...
Autori: Joanna Pałdyna
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27259

In this study was synthesized MCM-41 mesoporous silica by hydrothermal treatment and funtionalized with titanium in order to obtain mesoporous materials with high surfacea area and photocatalytic activity in photodegradation of organic compounds as antibiotics. The functionalization of the synthesized support material was achieved by impregnation from alcoholic solution. The obtained materials (MCM-41) and (Ti-MCM-41) were characterized by X-ray diffraction (XRD), scanning electron microscopy (S...
Autori: Cristina Orbeci
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27274

Environmental issues have received ascending attention in recent years due to the increase of their negative effects. Greenhouse gas emission levels have experienced an exponential increase in the last decades mainly on account of the development of the building sector. Life cycle assessment (LCA) of buildings is a proper tool to analyse the full environmental impact during their designed lifespan. Inventory databases have a shortage of local parameters in some countries and need to be developed...
Autori: Iosif Boros
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27289

Researches and analysis of heavy metals concentrations in the fish species exploited as a food source are of great interest due to long term toxic effects on human health even at very low concentrations. Therefore, we have conducted this study in an area of great interest in terms of aquatic biodiversity, but also of tourism and trade. Depending on the degree of toxicity in delta aquatic ichtyofauna, five heavy metals (Cr, Cu, Hg, Ni, Pb) and a metalloid (As) concentrations were measured in the ...
Autori: Adrian Burada
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27293

Arsenic removal from groundwater as drinking water source was investigated using electrocoagulation (EC) process with horizontal anodes of iron plate under galvanostatic regime. The current density of 5 A·m-2 was determined as the optimum operating conditions at the electrolysis time of maximum 25 minutes and pH ranged between 6.5 to 8.5, by which the arsenic concentration was reduced below 10 μg·L-1. The aspects related to the arsenic removal mechanism were discussed by Zeta...
Autori: Aniela Pop
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27327

The main objective of this study was to investigate the potential utilization of polyethylene terephthalate PET waste in cementitious matrix, as substituent to cement, to develop lightweight construction materials and for preventing chemical attacks or repairing various reinforced concrete structures. Composites containing different amounts of PET particles, as partial replacement to cement by weight, were characterized by destructive and non-destructive testing. So, the thermal conductivity, ul...
Autori: Ahmed Soufiane Benosman
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27381

A comparative study of humic substances (HS) extracted from raw sludge and its digested product was carried out in order to analyze HS evolution during sludge anaerobic digestion. HS content, elemental composition, functional groups, infrared spectra and ultraviolet absorbances were analyzed by means of chemical and spectrographic methods. The extracted HS were also fractionated by ultrafiltration in order to obtain their molecular weight (MW) distribution. The results showed that humic acids (...
Autori: Huan Li
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27390

End-of-life liquid crystal displays (LCD) represent a potential source of secondary raw materials for their relevant content of valuable materials, like plastics and metals. Furthermore, the combination of traditional and innovative recycling processes allows the recovery of indium, defined as critical raw material by European Commission. In this context, we have evaluated the environmental impacts of different management scenarios: incineration, the current recycling strategies and more inno...
Autori: Alessia Amato
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27401

Two montmorillonitic clays were modified with N-(methoxy-polyethylene glycol) ethylene diamine and tested as sorbents for removal of Rare Earths (REs) from aqueous solutions. Lanthanum was chosen as representing element of REs family and adsorption tests were performed with the aim of selecting a system with good uptake efficiency for the pollutant abatement in wastewaters. The effects of pH were studied and the properties of the obtained final materials were evaluated with simple model syst...
Autori: Elena Maria Iannicelli-Zubiani
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27408

In the present study the potential of a gene fusion between the arsB promoter from Synechocystis 6803 and the bacterial luxAB genes was evaluated to be used as a cyanobacterial bioreporter for monitoring the bioavailability of inorganic arsenic species. A whole-cell bioreporter strain, designated arsLux, was constructed based on this fusion. In concert with the specificity of the promoter presented earlier, luminescent signal could be detected upon exposure to arsenite, arsenate and antimonite, ...
Autori: Loredana Peca
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27473

This paper reports the possibility of using zinc ash as a secondary source for zinc oxide, which can be further used as white pigment. For the extraction of zinc from zinc ash, sulphuric acid was used. The impact of different parameters (ash fraction, contact time, sulphuric acid concentration and liquid:solid (L:S) ratio) upon the extraction degree of metallic ions from zinc ash was studied. The optimum conditions for the metallic ions extraction are: 20 % H2SO4, 30 minutes contact time, 1:1 L:...
Autori: Adina Negrea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27475

A low-cost magnetic zeolitic material was synthesized from coal fly ash by means of a new, simple method involving alkaline hydrothermal zeolitization of fly ash (FA) followed by low-intensity wet magnetic separation. Scanning electron microscopy with energy-dispersive X-ray analysis was applied to characterize the composition, microstructure, and morphology of the material. The mineral and synthetic zeolite phases were identified by powder X-ray diffraction. The obtained magnetic zeolitic m...
Autori: Annie Shoumkova
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27486

An apatitic calcium phosphate gel (HaG) was elaborated and used to treat municipal wastewater in a physicochemical cycle prior to the standard biological degradation process. Preliminary laboratory batch experiments outlined the kinetics of heavy metal sorption by monitoring the concentrations found in filtered fractions as a function of treatment time. On site experiments were performed in a municipal wastewater treatment plant by derivation of real wastewater into an experimental tank. In this...
Autori: Nathalie Lyczko
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27488

This study focuses on some mechanical properties resulted from the tensile testing of a set of green composites with a Dammar-based matrix and reinforcement material of silk, flax, cotton and hemp fabrics. To be precise, we have ascertained the characteristic curve, the resistance to and the elongation at fraction, as well as the modulus of elasticity for each set of samples from these composites and for a set of bioresin samples. With the help of an Electronic Scanning Microscope we captured im...
Autori: Ion Ciucă
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27516

An anaerobic-aerobic (An-Ox) sequencing batch reactor (SBR) was operated for the growth of phosphate accumulating organisms (PAOs), while an anaerobic-anoxic (An-Ax) SBR was used for the growth of denitrifying PAOs (dPAOs). Both reactors exhibited successful enhanced biological phosphorous removal (EBPR) performance. The sludge P contents in the two reactors increased from approximately 2% at the beginning of the operation to 9.1% (An-Ox SBR) and 7.3% (An-Ax SBR) after 140 d. The results of the...
Autori: Hansaem Lee
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27525

Absorption of gases into liquids, with chemical reaction, is an important unit operation useful in many fields, especially synthesis of new products and waste gas treatment. Gas treatment means the separation of pollutants: acid gases, organic sulphur compounds, and other contaminants which may be found in gaseous streams. The absorption into liquid is a process almost exclusively used for removal of contaminants. The removal refers to retention of the majority of acid gases present in high conc...
Autori: Maria Harja
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27555

The potential of Sphagnum moss peat to adsorb oxyanions (As(III), As(V), Sb(III), Sb(V) and Se(VI)) from aqueous solution was studied in batch mode. For arsenic (both species) and selenium, the results were negative: moss peat is not able to retain these oxyanion. For antimony, the hydroxyl and carboxyl groups from the Sphagnum moss peat surface seems to be responsible for Sb uptake. Kinetic studies were conducted for both Sb(III) and Sb(V) and a fast uptake process was observed, equilibrium bei...
Autori: Gabriela Ungureanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27565

This study dealt with investigation of arsenic removal from groundwater using electrocoagulation (EC) method in a batch mode by the Box-Behnken experimental design method. Effects of some cations like Ca, Fe, Mg, Mn and operating time on the removal were explored by an air injected EC reactor. The combined effects of these variables were analyzed by the quadratic model for predicting the highest removal efficiency of arsenic from groundwater. The arsenic removal efficiency was found to be depen...
Autori: Mehmet Kobya
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27584

Social upgradation results more postconsumer glass and plastic waste and continuously demands newer techniques for their management. This research proposes a new waste-to-waste management strategy by using waste glass for polyolefin degradation. For this purpose, waste glass is activated by mechanochemical treatment and resultant material is used for the thermal pyrolysis of polyolefin. Certain improvement in the product quality is achieved by selectivity towards more alkane fraction. ...
Autori: Pooja Singh
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27586

In this study, Ag/TiO2–P25 nanoparticles prepared via photodeposition method and its textural properties were characterized using X–ray diffraction (XRD), transmission electron microscopy (TEM), UV–vis diffuse reflectance spectroscopy (DRS), and N2 physisorption techniques. The cements modified with TiO2–P25 and Ag/TiO2–P25 nanoparticles were immobilized on tile plates, and their photocatalytic activity was evaluated versus the removal of Erioglaucine as the model o...
Autori: Mohammad A. Behnajady
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27589

The effects of gas addition on efficiency and CO2 emission were investigated with a compression ignition (CI) engine and a spark ignition (SI) engine operating with hydrocarbons-based fuels. Hydrogen rich gas (HRG) provided by an electrolyze, was aspirated into the air stream inducted in the engine cylinders. Investigation was conducted at engine light and medium loads and speeds, with relative low concentrations of HRG. For the CI engine, HRG addition up to 12.5% energetic fraction in fuel lowe...
Autori: Gheorghe Niculae
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27606

This study evaluates the behavior of freeze concentration of cheese whey (CW). Parameters studied were: Chemical Oxygen Demand (COD), Total Dissolved Solids (TDS), Suspended Solids (SS), Total Settleable Solids (TSS), pH and electrical conductivity (EC) in the concentrated cheese whey and in the ice. The final concentration of TDS reached was 25 ± 0.16 %wt for the liquid phase, which corresponds to a reduction of 83% of the initial volume. The COD in the ice fractions had lower values tha...
Autori: Freddy Belén
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27613

Pyrometallurgical recycling of lead from spent batteries entails secondary waste fractions generated in the blast furnace as iron stone and lead slags. For further purification of both fractions, hydrometallurgic processing is proposed. This paper focuses on purification of iron stone, in view of recovering metals (mainly lead) and of producing decontaminated iron stone fit for further recycling. The results demonstrate that iron stone is mainly composed of iron and lead; copper, zinc and antimo...
Autori: Bart Van der Bruggen
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27642

Recycling of solid plastic waste composed of post-consumer mixed polyolefines (polypropylene and polyethylene) was carried out by injection moulding of secondary material streams. The materials have been characterized by melt flow index (MFI), tensile, bending and impact measurements, density and differential scanning calorimetry (DSC). The sink-float technique was used to separate the polyethylene fraction, which was then blended into virgin polyethylene at different ratios and processed anew. ...
Autori: Laurens Delva
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27646

Two sets of simulated landfill reactors, namely conventional landfill (CL) and leachate recirculated landfill (RL) were operated to investigate the effect of leachate recirculation on the fractionation of Zn in municipal solid waste (MSW) landfill leachate. Zn in landfill leachate was fractionated into three fractionations: particulate and colloidal matter >0.45 μm, non-labile complexes <0.45 μm and free cations/labile complexes <0.45 μm. The result showed that the recirculatio...
Autori: Jun Yao
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27648

Magnesium wastes are among the gradually ascending and therefore challenging metal wastes, which are produced by many industrial activities. The purpose of this study is the usage of magnesium waste, a raw material in magnesium borate production by hydrothermal synthesis. Boron sources (boric acid (H3BO3) and boron oxide (B2O3)) react with magnesium wastes in order to synthesize the magnesium borate mineral of admontite (MgO(B2O3)3ꞏ7(H2O)). In addition to the synthesis from waste magne...
Autori: Azmi Seyhun Kipcak
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27657

This paper proposes a study on the estimation of daily solar irradiation (global and diffuse irradiation) under real-sky conditions and the validation of proposed estimation models by analyzing the most important statistical indicators. Two types of regressions are proposed for the estimation of solar daily global irradiation; the first type is based on the second order degree Ångström-Prescott correlations; the second type uses the second order Ångström-Prescott correla...
Autori: Elena Eftimie
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27670

Organoarsenic compounds are used extensively as swine feed-additives to promote animal growth and control diseases, e.g. roxarsone (4-hydroxy-3-nitrobenzenearsonic acid) and arsanilic acid (4-aminophenylarsonic acid) are usually overused in swine industry in China. As a cost-effective technology for animal manure treatment and reuse, composting is widely used for swine manure treatment. Therefore, the purpose of this study was to investigate changes of arsenic species and fractions during a full...
Autori: Rui Wang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27683

Sulfide bearing mine tailings generated through mining and processing of mineral ores is one of the serious problems around the world due to their potential environmental hazards. Current study focuses on vertical distribution and potential mobility of metals in New and Old tailings of a Lead and Zinc mining area of India. Mine tailing profiles sampled from New (0-500mm) and Old tailing (0-400mm) dams were chemically (pH, EC, Carbonate content, Cd, Pb, Zn and Mn levels) and mineralogically (usin...
Autori: Malik Anju
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27690

Atmospheric concentrations of PM2.5 and PM10 were measured in Beirut, Lebanon, for a period of 12 months. The daily average concentrations of PM10 and PM2.5 were found to be 51.3 ± 33.1 and 30.3 ± 9.4 μg.m−3, respectively, with corresponding maximum values of 359.7 and 208.6 μg.m−3. The annual average concentrations of PM10 and PM2.5 exceeded the World Health Organization’s standards by 150% and 200%, respectively. The mean concentration of coarse particles ...
Autori: Wehbeh Farah
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27696

The quantification of heavy metals in dry and wet weather derived (runoff and snowfall) sediment from roads, under three different environmental conditions, has indeed the potential to allow improved understanding on urban diffuse pollution. With that aim, the reported study determined the concentrations of Cd, Cu, Pb, Ni, Cr and Zn in road sediment, which are reported to be found in elevated level in the road-traffic environment, and associated pollution levels at four different sites, represen...
Autori: Sudip K. Pal
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27776

Geocomposite materials consisting of lightly cemented mixtures of expanded polystyrene beads (EPS) and backfill soils are commonly used as fillers and for the construction of light weight embankments. The constant normal stress (CNS) and constant volume (CV) direct shear parameters as well as the relationship between gradation properties of four residual granular backfill soils and direct shear parameters of lightly cemented mixture of EPS and backfill soils was evaluated. The maximum density an...
Autori: Felix Okonta
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27771

The aim of this paper is to show the results of two methodological approaches applied for decontamination of the Midia Port dredged sediment to assess their potential reusability. Firstly, the sediment samples were defined in physical, chemical, microbiological and ecotoxicological terms. The results were compared to the limit values established by environmental regulations for dredged sediment management. Some sediment samples exposed a very high concentration of hydrocarbons; the sediments wer...
Autori: Irina Catianis
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27770

This paper investigated the compressive strength and thermal conductivity of water and air cured Portland cement-fly ash-silica fume mortars. The results showed that density, compressive strength and thermal conductivity of blended cement mortars with fly ash were lower than Portland cement control. However, blended cement mortars that contained silica fume as replacement cement both in binary and ternary phase were higher than fly ash mixes and tends to increase with increase silica fume used a...
Autori: Chalermphan Narattha
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27731

In this paper, the typical measurement techniques and production procedures defined in the UNI-EN guidelines for ceramic manufacture are taken into consideration to evaluate the properties and the characteristics of the bricks produced by using a mixture containing cubilot slag. The results of the experimental tests demonstrate that these measurement techniques are not enough to define the safety of the waste bricks. Up to now, UNI-EN guidelines for ceramics do not define crystallinity measureme...
Autori: Domenico Luca Carni
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27787

Water sea pollution is influenced mainly by anthropogenic causes due to industrial and municipal activities which affect the quality of sea water, sediments and the whole ecosystem. In this paper, the correlation between contamination sources and the environmental quality of marine sediments was analyzed through multivariate analysis, in particular Principal Components Analysis (PCA), Cluster Analysis (CA) and Correlation Analysis. Considering the case study of Mar Piccolo in Taranto (Ionian Sea...
Autori: Claudia Labianca
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27793

The research has been focused on concretes in which the continuous phase is some kind of polymeric resin and the discrete phase is some type of mineral aggregate. Such composite materials are known as Polymer concretes (PC) and boast several advantages such as lower weights, higher resistance to corrosive environments and chemical attacks, faster curing and lower permeabilities. In PC the inorganic fraction can reach up to 90% of the total and is made up of aggregates such as sand and gravel. Th...
Autori: Paolo Pozzi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27799

The aim of this paper was to investigate the possibility of incorporation non-metal fraction (NMF) in concrete products as a substitute for aggregate on industrial scale, while other studies are mostly based on NMF incorporation in concrete only on laboratory scale. Mineral filler was supplemented with 5, 10, 15 and 20 wt.% NMF from waste printed circuit boards (WPCBs) and its influence on concrete quality was assessed based on compressive and tensile strength conducted on laboratory and indust...
Autori: Vitomir Premur
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27857

The goal of the present work is to evaluate the efficiency of bioventing on low permeability soils stimulated with hydraulic fractures and polluted by a mixture of semi-volatile and non-volatile hydrocarbons. A synthetic non-aqueous phase liquid (NAPL) composed of 5 hydrocarbons is prepared: 1,2,4-trimethylbenzene (TMB), methylcyclohexane (MCE), n-dodecane (n-C12), n-decane (n-C10), n-eicosane (n-C20). The capacity of indigenous bacteria to degrade high NAPL concentrations is evaluated with biov...
Autori: Dimitra N. Tzovolou
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27849

Within this study a total content of 20 elements was determined in 25 soil samples taken from the vicinity of the "Buchim" mine, Republic of Macedonia, covering an area of 14.2 km2. The results have been compared to new Dutchlist and NOAA standards and it was concluded that the content of As, Cd, Cu, Pb and Zn in most of the samples is over the corresponding optimal or action values probably due to the anthropogenic activities. Thus As values ranged 13.1-225 mg kg-1 with 20 above the o...
Autori: Todor Serafimovski
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27844

The Danube River forms one of the largest and most complex deltas at the Black Sea, being a Biosphere Reserve, UNESCO World Heritage and Ramsar site. This study assesses the spatial variability of arsenic contamination of the water in the Danube Delta. Water samples were collected during all seasons in 2013 from the south-east of the Danube Delta and analyzed through HG-AAS method for arsenic. Data were handled using two different approaches. First, a complex hydrological model was compiled, ...
Autori: Gabriel Gati
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27884

The aim of this study was to determine how temperature conditions (max. 72oC, 81oC and 43.5oC) during sewage sludge composting affect the distribution of organically bound heavy metals in humic substances (HS). To accomplish this, the content of Cu, Ni, Zn and Fe was measured in the two main fractions of HS, humic acids (HAs) and the fulvic fraction (FF). In the feedstock, the FF was mainly responsible for binding all metals except Ni. During composting in the two series with thermophilic con...
Autori: Dorota Kulikowska
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27894

In this paper, several image analysis techniques have been applied aiming to obtain useful information regarding the processing of municipal solid waste polymers. An automated color extraction method has been applied in order to quantize the color distribution in the polymer wastes aiming their resource and time-efficient separation according to their color. Also, by processing different density fractions from the polymer waste the color of the final material has been predicted, as well as th...
Autori: Silvia Patachia
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27994

Little is known about the degradation kinetics of sewage sludge, sanitized with Ca(OH)2, in soil. Thus, this work aimed to monitor the degradation of limed sludge, under field conditions, when applied on soil surface or incorporated into the soil. The limed sludge was applied in dystrophic Inceptisol at a dose of 500 kg ha-1 yr-1 of total nitrogen. The mineralization process in the soil was monitored for 131 days. Samples of organic material were collected for analysis of total and easily oxi...
Autori: Isabela Diniz
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27995

The polyhydroxybutyrate (PHB) production by photoautotrophic cultures is a potential eco-sustainable process to produce bioplastics. The biosynthesis of PHB by cyanobacteria meets a twofold target: the use of CO2 as feedstock alternative to the fossil resource used in the conventional processes; the contribution to the reduction of the CO2 concentration in the atmosphere. This contribution reports results of a study regarding the optimal growth conditions for cyanobacteria to produce PHB unde...
Autori: Roberta Carpine
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28021

Among the usual geodetic methods of vertical deformations measuring of structures and natural objects, geometrical levelling is one of the most accurate, but also requires compliance to specific conditions of slope and terrain accessibility. Where geometrical levelling is difficult or impossible to apply, the trigonometric levelling can be a viable practical solution, if there are followed a series of procedures to improve the accuracy of the final results. For the case of classical geodetic me...
Autori: Constantin Chirilă
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28049

A simultaneous hierarchical classification of groundwater in the Banat Plain-southwestern Romania and associated characteristics such as As(III), As(V), total As, trace metals (Al, Cd, Cr, Cu, Fe, Mn, Ni, Pb, Zn), pH and redox potential using Fuzzy Hierarchical Cross Clustering Algorithm was carried out. In samples containing more than 10 μg/Ltotal As (13.9 – 77.3 μg/L), the As(V) species represented 57±20% and 73±18% in the others. Arsenic speciation pattern was in agr...
Autori: Marin Senila
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28059

The goal 12 of the 2030 Agenda for Sustainable Development takes into consideration the responsible consumption and production in the perspective of circular economy. The agri-food sector is more actively involved in these initiatives, because it offers the possibility to exploit waste and by-products, by adopting suitable biotechnologies. Such processes can be carried out either under aerobic conditions, for the production of compost, or anaerobically, for the production of biogas. In this work...
Autori: Veronica Novelli
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28078

Leather processing is one of the highly polluting industries, due to generation of significant quantities of tanned and untanned wastes. Untanned wastes are less contaminated with chemicals and a better source of high value products such as collagen rather than tanned or finished leather wastes. In the present study, collagen dissolution substances (CDS) were prepared from bovine limed split wastes as value added products, by treating leather wastes with sodium hydroxide and fermented dairy b...
Autori: Gökhan Zengin
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28095

The combustion behavior of several polymers was studied with a cone calorimeter, while the samples were based on a recycled acrylonitrile-butadiene styrene (ABS) and as additives were considered: organic montmorillonite (OMT) and a mixture of two fire retardants (FR). The samples structure and thermal properties are characterized by means of Scanning electron microscopy (SEM), X-ray Powder Diffraction(XRD) and Energy-dispersive X-ray spectroscopy (EDX) and cone calorimeter. The main objective o...
Autori: Tudor Mihai Simionescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28098

In the present research, the intensity of contamination with heavy elements Vanadium (V) and Arsenic (As) in the coastal sediments of Bandar Abbas is gauged and rated using the method of Atomic Absorption Spectroscopy. All processes of sampling and assimilation of sediments are performed according to the guideline of the Manual of Oceanographic Observations and Pollutant Analyses Methods (MOOPAM) Standard issued by the Regional Organization for the Protection of the Marine Environment (RAPMI).T...
Autori: Akbar Elsagh
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28105

Arsenic-containing acid wastewater produced in the mining and smelting process will bring great harm to the environment, while to treat arsenic-containing wastewater with iron salt and lime is an economical and effective method. In this paper, iron salt was added to co-precipitate the arsenic and heavy metals, the pH value of arsenic containing acid leaching solution was adjusted by adding of lime. The stability of co-precipitates was also investigated in this study. The results show that the ir...
Autori: Yongliang Wang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28121

The present study represents an extension of ergosterol production by Saccharomyces cerevisiae fermentation processes using oxygen-vector by establishing the influence of the analyzed main factors, such as aeration efficiency and hydrocarbon concentration. The study has been developed for batch and fed-batch fermentation systems and has been focused on the variation of ergosterol content inside the yeast cells during the fermentation cycle in correlation with hydrocarbon volumetric fraction, COV...
Autori: Corina Ciobanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28130

There are considerable environmental and health and safety concerns regarding liquid crystal display (LCD) waste glass because of the waste electrical and electronic equipment (e-waste) that is deposited in landfills. In current study, the effect of variation in LCD waste glass on the deconvoluted fractions of silicon centers of metakaolin geopolymers has been comprehensively investigated to discover the underlying mechanisms governing the performance. Solid/liquid ratio affects the kinetics of ...
Autori: Kang-Wei Lo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28146

Molybdate anions are used in a lot of fields and represent an essential trace element for plant and animal life; however, excessive amounts can cause adverse effect on various organism and environment. Therefore, in the present paper the adsorption performance of MgnFe- layered double hydroxides in the removal process of molybdate from aqueous solutions was studied. The layered double hydroxide (LDH) was synthesized by co-precipitation at low oversaturation method. Different ratio between Mg and...
Autori: Alin Golban
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28152

The pyrolysis of frying palm oil was studied in continuous stationary process, in a micropilot plant. The main factors affecting the products yields are temperature and residence time. For the studied parameters range (temperature: 475oC - 630oC and residence time: 120 s- 240 s), the gas yield varied between 7.9% (w/w) and 63.3% (w/w), related to feed. Unsaturated hydrocarbon yields (olefins) can reach 24-29% (w/w) related to feed, at the right processing parameters, the main products having goo...
Autori: Ana Maria Sivriu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28162

Distribution of solid particles in the atmosphere around the pollution sources has an important role in decision making to oppose with air pollutants. This study reports the concentration and distribution of 11 heavy metals including Cu, Co, Ni, Cd, V, Ti, Mo, Cr, Pb, As, and Hg emitted from 6 incinerators (A to F) with various feeds and operating conditions to determine the extent of exposure for industrial and residential areas. These incinerators located at Petrochemical Special Economic Zone...
Autori: Akbar Pirbadali-Somarin
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28166

The valorization of a metallurgical waste (i.e., an iron-rich slag) as raw material for the fabrication of high hardness glass-ceramics using differential thermal analysis, X-ray diffraction, X-ray fluorescence and scanning electron microscopy was investigated. The melting of the slag was aided by the addition of waste glass cullet (WGC) and the vitrification field of this system was investigated. The non-isothermal crystallization kinetics of the parent glass with the highest slag content was s...
Autori: Erika Iveth Cedillo-GonzĂĄlez
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28168

Inorganic ceramic materials is receiving more attention in recent times due to their unique characteristics which include different pore structures, hydrophilic surfaces, high chemical, thermal and mechanical stabilities that offer avenues for application in water treatment. In the present work, cost-effective clay ceramic water filters of different designs were developed from clay (50, 60, and 70) %, sawdust (15, 20, 25, and 35) %, grog (5, 10 and 15)% ratios plus 5% bone char by volume and ...
Autori: Enyew Amare Zereffa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28196

Copper and Zinc co-doped titania nano photocatalyst (Cu-Zn-TiO2 NPC) was fabricated and characterized using room temperature X-ray diffraction (XRD), field emission electron microscopy (FESEM) with high-resolution transmission electron microscopy (HRTEM) and energy dispersion X-ray (EDX). X-ray diffraction studies of the Cu2+-Zn2+/TiO2 show the presence of anatase phase TiO2 and in the sample prepared from 0.05, 0.10, 0.15 and 0.20 mmol have also shown the presence of anatase phase only. The ph...
Autori: Tentu Nageswara Rao
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28198

LED waste quartz sand (LEDWS), which is a prominent by product of the LED manufacturing process, may contaminate the environment because it comprises specific heavy metals (e.g., As and Cu), which are hazardous ingredients to the environment when disposed of improperly. Therefore, this study investigated the use of light-emitting diode (LED) waste quartz sand to partially replace Portland Type I cement (OPC) to evaluate the feasibility of reusing it as a pozzolanic material. The SiO2, Na2O, and ...
Autori: Kae-Long Lin
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28207

Printed circuit boards are the most important component of any electrical and electronic device. The average metal content in waste printed circuit boards is ~30-35% whereas the rest of the material is a non-metal fraction (NMF). Metals in the waste printed circuit boards are recycled for their value whereas the NMF is mostly sent to landfills or incinerators for disposal. The circuit board laminates contain flame retardant chemicals that pose potential hazards to the environment and to public h...
Autori: Amit Dhir
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28216

Techniques such as composting, a controlled process of decomposition of organic materials, have become fundamental to minimize the problems associated with the organic fraction of urban solid waste, as the potential to cause damage to public health, the environment and, consequently, to economic and administrative aspects can be related to this kind of waste. Microbial activity is also highlighted as a relevant factor since the microorganisms are fundamental in the degradation of organic matter...
Autori: Priscila da Costa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28222

In this article, issues of environmental pollution due to long-range atmospheric transport of heavy metals are considered. Researches of recent sediment cores of Lakes Liunkunlampi and Raivattalanlampi from the Republic of Karelia were carried out. The purpose of the study was to give a detailed environmental and geochemical assessment of the recent sediments in these small lakes located in the southwestern part of Karelia. The scope of the study covers the area of the southwest of Karelia (Russ...
Autori: Zakhar Slukovskii
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28229

Even though carbonate fraction of soils significantly influences soil contaminant retention, there are few reports in the literature on the influence of temperature on contaminant retention of carbonated soils. Therefore, this study was conducted to investigate the effect of temperature on buffering capacity in carbonated and decarbonated kaolinite and on changes in intensity of x-ray diffraction for major peak of kaolinite. To achieve this aim, samples of kaolinite containing 2.5% carbonate and...
Autori: Vahid Reza Ouhadi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28231

An experimental inquest was performed to quantify the turbulent flow characteristics near the eroded region of an artificial sidewall bank at three different flow depths, and a comparison study is made between before and after erosion for two Reynolds numbers. Instantaneous flow velocities were taken with an acoustic Doppler velocimeter (ADV) at near bank of the vertical side wall. The mean flows and other turbulence quantities such as Reynolds shear stress, turbulent intensities, and turbulent ...
Autori: Krishnendu Barman
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28264

Three scenarios for the management of Municipal Solid Waste (MSW) produced in the study area of Bari (Southern Italy) were defined and evaluated in terms of separately collected material and fate of the residual fraction. The first scenario represented the bring points MSW separate collection system in the current configuration with a collection rate approx. 40%. The second scenario considered the study area in the optimal configuration, with a percentage of separate collection > 80% obtaine...
Autori: Sabino De Gisi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28293

The steady increase in separate waste collection has highlighted the urgent need to adequately deal not only with urban waste (differentiated and undifferentiated) but also with special waste produced by separate waste collection and recycling processes. Source collected municipal solid waste produces different waste streams. One of this is the organic fraction of municipal solid waste (OFMSW). This fraction is central for circular economy, since it can be further transformed in order to recove...
Autori: Ivana Moscato
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28302

Zinc oxide and strontium doped zinc oxide nanoparticles were synthesized through hydrothermal route. The synthesized nanoparticles were characterized by UV, FTIR, SEM, X-Ray diffraction (XRD) and energy dispersive x-ray (EDX) spectroscopic techniques. The optical band gaps were calculated to be 3.16EV and 2.90EV for ZnO and Sr-ZnO nanoparticles, respectively. FTIR confirmed the incorporation of the Sr into ZnO nanoparticles. Average particles size of undoped ZnO and Sr-doped ZnO nanoparticles wa...
Autori: Fazal Akbar Jan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28323

The present study describes the facile synthesis of silver nanoparticles (AgNPs) by green method using aqueous extract of Gazania rigens. The size, morphological, compositional and optical properties of silver nanoparticles were examined through X-ray diffraction (XRD), Energy Dispersive X-ray spectroscopy (EDX), Scanning Electron Microscope (SEM), and UV-Vis spectroscopy respectively. Ultraviolet-Visible spectra showed the absorbance band between 425–460 nm which indicated the synthesis o...
Autori: Tayyaba Shahzadi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28349